Anisotropic confinement of chromophores induces second-order nonlinear optics in a nanoporous photonic metamaterial

09.02.2021 Second-order nonlinear optics, in particular Second-Harmonic Generation (SHG) is the base for a large variety of devices aimed at the active manipulation of light. Within an European collaboration we demonstrate that embedding chromophores in conical silica nanopores results in a photonic metamaterial exhibiting SHG, see the article entitled "Anisotropic confinement of chromophores induces second-order nonlinear optics in a nanoporous photonic metamaterial", published in Optics Letters.

 

"Precursor Film Spreading during Liquid Imbibition in Nanoporous Photonic Crystals" published in Physical Review Letters

01.12.2020 Optofluidic study on liquid imbibition dynamics entitled "Precursor Film Spreading during Liquid Imbibition in Nanoporous Photonic Crystals" has been published in Physical Review Letters. The paper resulted from a collaboration with Luisa Cencha, Claudio Berli and Raul Urteaga from Argentina.

 

"Giant electrochemical actuation in a nanoporous silicon-polypyrrole hybrid material" published in Science Advances

30.09.2020 Silicon Flexes Muscles: Our article "Giant electrochemical actuation in a nanoporous silicon-polypyrrole hybrid material" has been published in Science Advances, see also a press release by DESY (English/German) or listen to the podcast episode "Künstliche Muskeln - Poröses Silizium dehnt sich auf Knopfdruck aus", Forschung Aktuell - Deutschlandfunk (05.01.21).

 

Article "Ionic liquid dynamics in nanoporous carbon: A pore-size- and temperature-dependent neutron spectroscopy study on supercapacitor materials" published

27.05.2020 Our article "Ionic liquid dynamics in nanoporous carbon: A pore-size- and temperature-dependent neutron spectroscopy study on supercapacitor materials" has been published as Editors' Suggestion in Physical Review Materials.

 

 

Ionic liquids imbibed in nanoporous carbons are promising hybrid materials for electrochemical energy storage, conversion and harvesting. These functionalities crucially depend on the ionic mobility in the pore space. Here we demonstrate that quasielastic neutron scattering, specifically the so-called fixed energy window experimental technique, is particularly suitable for a fast access of the confined ionic liquid’s dynamic landscape as a function of pore-size and temperature. Compared to the bulk we find reduced self-diffusion mobilities. However, despite this slowing-down, the temperature range of the liquid state upon nanoconfinement is remarkably extended to much lower temperatures, which is beneficial for potential technical applications of such liquid-infused solids.

 

Book "Soft Matter in Geometrical Confinement" published

13.03.2020 Book "Soft Matter in Geometrical Confinement" published.

The book "Soft Matter in Geometrical Confinement: From Fundamentals at Planar Surfaces and Interfaces to Functionalities of Nanoporous Materials"  has been published within the part  "Soft Matter and Biomaterials on the Nanoscale: The WSPC Reference on Functional Nanomaterials" of the World Scientific Series in Nanoscience and Nanotechnology.

 

  1. Self-Assembly of Liquid Crystals in Nanoporous Solids for Adaptive Photonic Metamaterials
  2. Minisymposium: Fluids in Nanoporous Media
  3. DASHH PhD Student Position
  4. Nondestructive high-throughput screening of nanopore geometry in porous membranes by imbibition

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News

  • 23.04.2026 Lehmann Prize awarded to Patrick Huber

    🏆 Congratulations to Patrick Huber on receiving the Volker Lehmann Prize for the most outstanding talk at the 2026 Porous Semiconductors Science and Technology Conference (PSST2026) in Naples, Italy.

    💧 His presentation, “Nature’s Blueprint: Water-Enabled Functions in Hierarchically Porous Silicon,” showcased key research directions of the Cluster of Excellence BlueMat: Water-Driven Materials. 

    🏆 The Lehmann Prize honors Volker Lehmann, who—together with Leigh Canham and Ulrich Gösele - co-discovered the quantum confinement effect in silicon.

  • 22.10.2025  Water as an energy carrier: nanoporous silicon generates electricity from friction with water

    Exciting news! Our new publication in Nano Energy presents a novel way for converting mechanical energy into electricity – by harnessing water confined in nanometre-sized pores of silicon as the active working fluid (press release).

  • 29.09.2025 Colossal Effect of Nanopore Surface Ionic Charge on the Dynamics of Confined Water

    In a recent publication, we report a particularly rewarding result from a French-German collaboration linking Hamburg, Rennes, Grenoble and Paris, with key neutron scattering experiments carried out at the high-flux neutron reactor of the Institut Laue-Langevin in Grenoble, France. 

    We show that water behaves very differently when confined to tiny nanopores—and that surface charge makes all the difference. Adding ionic charges to pore walls dramatically slows down water motion, not just in the vicinity of the pore wall but throughout the entire pore. This long-range control goes far beyond simple wetting effects and highlights surface charge as a powerful tool for using water as a nanoscale working fluid in water-driven materials, membranes, and nanotechnologies.

  • 09.09.2025 When symmetry breaks in tiny spaces

    Nanopores unlock hidden chirality in exotic liquid crystals – with the observation now made by us within an international cooperation with Ukraine, France and Poland, they might find even wider usage in energy storage or conversion or tunable lenses (see press release).

  • 22.05.2025 Cluster of Excellence "BlueMat: Water-driven materials" approved

    BlueMat has been awarded funding through the Cluster of Excellence program (ExStra)!

    The application process was challenging: out of a total of 143 draft proposals for new clusters of excellence, only 41 were invited to submit a full proposal. In this second round, the new applications competed with the 57 already established clusters. Of a total of 98 applications submitted, only 70 were approved. The Cluster of Excellence will initially be funded for seven years until 2033.

    We would like to thank all of our partners for their hard work. The whole team is energized and eager to begin bringing our vision to life. Stay tuned for updates as we embark on this exciting journey!