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Optical Birefringence Study on Confined n-Hexane

17.07.2009
Surprisingly, spatially nano-confined liquid n-hexane is still an isotropic liquid: We did not find any hints of collective orientational order as a function of filling of glass capillaries with 7 nm mean diameter and 400 micrometer length. A combined optical birefringence/vapour sorption isotherm study reporting this message was published in Physical Review B today. The absence of any orientational order in the confined liquid state highlights the importance of an anisotropic crystallization process named after Percy W. Bridgman (a Harvard scholar and Nobel Laureate) for the occurence of preferred orientations upon solidification of n-hexane and medium-length n-alkanes in nanochannels of mesoporous silicon.

X-ray diffraction study on n-hexane in porous silicon

March 2009
Crystallization study on n-hexane in silicon nanochannels published in Physical Review Eand a study on phase transitions and molecular dynamics of spatially nanoconfined n-hexadecanol (a joint project with the research group of Rolf Pelster) published in Physical Review B.

Capillary Rise of Water in Nanopores

22.06.2009
Study on capillary rise dynamics of water in hydrophilic nanopores published in Physical Review E. A ray-tracing movie which illustrates this spontaneous imbibition process in mesoporous silica glass (monolithic Vycor) can be downloaded here. It employs the Liquid-Surface-Simulation Macro package (LSSM) for POV-Ray by Tim Nik Wenclawiak.

EXIST-priME-Cup

05.06.2009
Anke Henschel und Simon Grüner sind gemeinsam mit René Berwanger aus der Arbeitsgruppe Pelster als Sieger aus dem Master Cup in Saarbrücken im Rahmen des EXIST-priME-Cup hervorgegangen.
Glückwunsch an die drei!

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News

  • 23.04.2026 Lehmann Prize awarded to Patrick Huber

    🏆 Congratulations to Patrick Huber on receiving the Volker Lehmann Prize for the most outstanding talk at the 2026 Porous Semiconductors Science and Technology Conference (PSST2026) in Naples, Italy.

    💧 His presentation, “Nature’s Blueprint: Water-Enabled Functions in Hierarchically Porous Silicon,” showcased key research directions of the Cluster of Excellence BlueMat: Water-Driven Materials. 

    🏆 The Lehmann Prize honors Volker Lehmann, who—together with Leigh Canham and Ulrich Gösele - co-discovered the quantum confinement effect in silicon.

  • 22.10.2025  Water as an energy carrier: nanoporous silicon generates electricity from friction with water

    Exciting news! Our new publication in Nano Energy presents a novel way for converting mechanical energy into electricity – by harnessing water confined in nanometre-sized pores of silicon as the active working fluid (press release).

  • 29.09.2025 Colossal Effect of Nanopore Surface Ionic Charge on the Dynamics of Confined Water

    In a recent publication, we report a particularly rewarding result from a French-German collaboration linking Hamburg, Rennes, Grenoble and Paris, with key neutron scattering experiments carried out at the high-flux neutron reactor of the Institut Laue-Langevin in Grenoble, France. 

    We show that water behaves very differently when confined to tiny nanopores—and that surface charge makes all the difference. Adding ionic charges to pore walls dramatically slows down water motion, not just in the vicinity of the pore wall but throughout the entire pore. This long-range control goes far beyond simple wetting effects and highlights surface charge as a powerful tool for using water as a nanoscale working fluid in water-driven materials, membranes, and nanotechnologies.

  • 09.09.2025 When symmetry breaks in tiny spaces

    Nanopores unlock hidden chirality in exotic liquid crystals – with the observation now made by us within an international cooperation with Ukraine, France and Poland, they might find even wider usage in energy storage or conversion or tunable lenses (see press release).

  • 22.05.2025 Cluster of Excellence "BlueMat: Water-driven materials" approved

    BlueMat has been awarded funding through the Cluster of Excellence program (ExStra)!

    The application process was challenging: out of a total of 143 draft proposals for new clusters of excellence, only 41 were invited to submit a full proposal. In this second round, the new applications competed with the 57 already established clusters. Of a total of 98 applications submitted, only 70 were approved. The Cluster of Excellence will initially be funded for seven years until 2033.

    We would like to thank all of our partners for their hard work. The whole team is energized and eager to begin bringing our vision to life. Stay tuned for updates as we embark on this exciting journey!

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